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Hi SloopjohnB - I've had a look through my Haynes manual for the 1994 diesel Clio and it says the heated rear window relay is number 2. (Yeh I know that's a fat lot of help) but in the picture it appears to be one on the right. On the right there are 2 relays one above the other and the one they refer to as "heated rearscreen" is the bottom one. Have you checked if current is getting to the rear screen because in the past I have seen the same symptoms where a faulty earth or connection was at fault.
Currently in madnoel10's garage:
Honda Civic 1.4l