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The Laguna system is based on the MS5000 but the two are not identical. The MS5000 manual (downloadable from VDO's website) is probably the best guide you'll get for Carminat, but don't expect all of the features to be present or to work exactly as described.
From a harware point of view, I doubt they're compatible. If I recall correctly, the MS5000 has the screen built into the main navigation unit for starters.
But if you're looking at replacement map discs, then ones that are compatible with the MS5000 should work with Carminat.
Currently in Horatio's garage:
2010 Laguna III Initiale.